Rick is right. If you are going to purchase a second PSU, you can probably get one with the required wattage for about the same as you'd be spending for the one to add.
But if you already have the second PSU and have the knowledge necessary to do it, then it is a good alternative to buying a new PSU. The main things to keep in mind is that some PSUs, such as those from Compaq, use a latching voltage to stay on. It is pretty easy to bypass but takes a little electronics experience and soldering. Then there is the power switches that need to be latched together which is again easily done but requires a little knowledge.
The thread Rick pointed you to can give you more info.
Oh, almost forgot.. If you do this mod, don't stand in water and dont leave it in the middle of a room where someone can trip over it. And don't cut the ground prong off the power cords.. Safety First