Boot.ini failure

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Whenever my Pc boots up it comes up with "Boot.ini Failure booting from C:windows" or words to that effect, ( Im using Windows XP Pro )but once the computer boots up it works fine, can someone please tell me what might have happened here & is there a simple fix, Ive run a Anti-virus & Anti-spyware scan, both are showing everything as clean but this boot up failure still shows, I would be grateful of any assistance Thanks
 
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