Two new HD's With XP

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Have new pc, and also new at building pc's. I bought one WD 36g raptor sata , and one 120g sata min. HD. I cant get either drive to boot up with xp. With both drives hooked up i can't even get my cd/rw drive to pick up my os disk. I have raid controller driver loaded. My mobo is soyo athlon ap 2500+. I have dual sata slots on my board. Can anyone tell me why nothin will work? I've trie it all!!!!
 
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