how would i overclock an Nvidia GeForce 6600gt PCI-E?

Overclocking a piece of hard ware can often cause damage, especially if you don't have a high quality PSU. I do not recomend overclocking. It may even void your warranty. If you want to speed up your PC look here

If you are aware of this and still want to do it, let me know and I'll see what I can do.

Regards,

Korrupt
 
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