A great little intro on the different RAID types can be
found here on Wikipedia.
RAID stands for "Redundant Array of Inexpensive Disks". It was devised years ago as a means of fast/cheap data backup by writing the same data to multiple drives at the same time. As such, "RAID-0"
technically is NOT a true RAID format because there is NO data redundancy. The benefit of RAID-0 is that it is fast because it splits the data up, reading/writing from/to two drives at the same time. But don't get the mistaken idea that it makes everything twice as fast, because the data must be processed. So you'll see little or no performance gain... even a loss... with "tiny" files (under a meg), but a really nice speed boost with
big files like DVD's, large games, etc. But with no redundancy (meaning no data is duplicated), if one drive goes dead in a RAID-0 array, you lose EVERYTHING on BOTH drives.
RAID-10 is a combination of RAID-1 (mirroring drive one on drive 2) plus RAID-0, combining the speed of "0" with the security of "1", but takes FOUR drives, half of which is backup, so you only get half the space. A bit pricey wasting two drives on a realtime backup.
RAID-5 takes only three drives to do the same as RAID-10, but it's slower than RAID-0/1/10.
JBOD ("Just a Bunch Of Disks") isn't a RAID format at all, but lets you string a whole bunch of little drives together so they look like one big drive. NO performance benefit, but wastes almost no space when formatting your drives, giving you FAR more space than if you formatted them individually. If you have a bunch of old drives lying around gathering dust, JBOD can be useful.
Once you've picked your desired RAID format, you must go into the BIOS and set your system to use the built-in RAID controller instead of the standard controller. (There will be other BIOS settings as well. Check the manual.) When you boot your new computer, there will be a point in the Asus startup routine when it prompts you to hit a key to enter the RAID setup utility, a simple built-in program. From there, it will let you choose your RAID configuration and format your drives. After that is when you boot from the XP CD and install Windows from scratch. Windows will prompt you install a "RAID/SCSI controller" from floppy first. The manual will tell you how to make such a disk. I made one by running the driver-maker program on the Asus driver CD on another PC. That's the easiest way. Check the manual on other methods (you might be able to just load the driver straight off the CD, depending on how the Asus bios has changed since I did it.)
If you have all your ducks in a row ahead of time, it's a fairly easy process. Your MoBo's user manual should include an entire section on setting up your system to use RAID. Download the manual from Asus and read up on it you're concerned.
PS: Oh, I almost forgot, when using RAID, every drive must be the EXACT same size and speed. JBOD doesn't care about size/brand/speed/etc.