Firstly I think you need the manual. It should be on your CD (pdf file)
Secondly, It's not advised to bump up the overclock in large increments. When overclocking you should raise the FSB/Core frequency in smaller steps and test after each change for stability.
If the BIOS automatically raises CPU voltages when you are increasing the FSB/Core freq. then that needs to be monitored-or in some cases changed manually. A lot will depend on what CPU cooling you have and the CPU's VID (stock voltage).
You should also have "Execute Bit Support", "Limit CPU Max Value" (
screen 8 of this review), "Intel EIST" (screen 16) all set to "Disable" , as well as Intel SpeedStep and C1E if they are available in the BIOS.
I'm not sure what you are saying regarding overclocking one core only - the overclock should affect both cores of your CPU.
Before any overclocking I would recommend you read up on the manual, post screenshots of anything you are unsure about and read up on basic overclocking procedure, and above all, if you are using a stock Intel cooler then I
stress that
overclocking is not a good idea.
These Youtube clips (part
1 and
2) and the sidebar links to videos of BIOS/Jumper settings so you can familiarize yourself with the setup. But before going any further RTFM, and be aware that although XFX advertise this as a 1800FSB+ board (i.e.for overclocking), damaging the board through overclocking (too much voltage for MCP/SPP) will void your warranty.
Finally,
here is an overclocking guide for nVidia SLI chipset boards.
To fully help you I would need for you to know your way around the BIOS and be aware of the terminology. A misunderstanding regarding voltage options especially can lead to very bad results.