There is NO option for that choice that I am aware off. WAY BACK in windows, I configured
1) C:\ only for the OS
2) D:\ for shrinkwrap software (ie products I bought)
3) E:\ for user data
With 100GB on C:\ you can certainly allow all programs on C:\ and create a \user\yourLogin\ on the 1TB drive
for data. The issue will be to place a shortcut from c:\user\yourLogin\My Documents -> \user\yourLogin\My Documents on the 1TB and being resolute to storing files there {eg *.doc, *.xls, PICS, Music, ... }
Wherever you install programs, remember, there is ONLY ONE registry and it is ALWAYS on C:\ so
programs installed elsewhere can be a recovery problem.