100%? No, but when you read the articles on ice core samples, you will know whyThat is correlation - it’s PROBABLY accurate but we can never be 100% sure of anything that happened before we had actual humans recording it.
they are relied on as heavily as they are. The gasses they trapped are just as viable as they were the moment they were frozen, to just wait until we needed them.
They have been referred to as time machine's for good reason.
Check this out:
Is Ice Core Dating Reliable? - Radiocarbon lab Beta Analytic
Measurements on ice cores can be resolved to within a decade which represents orders of magnitude higher resolution than sediment cores.