yeah, you can assign two GPUs for different jobs. As long as they're from the 8 series and above. You can even do it with ATI+Nvidia cards.
http://www.overclock.net/graphics-cards-general/508305-howto-ati-nvidia-physx-guide.html
and here's how you do it if you're interested.
1. Turn off your computer and PSU
2. Install your 9600 GT on the 2nd PCie slot
3. Turn on your computer and uninstall your current driver.
i. Go to My Computer's properties
ii. Device Manager
iii. Expand the Display Adapter
iv. Right click on your card and click Uninstall; also, tick the option "Delete the blah blah" and click OK.
v. Once done, if asked to restart, DO NOT RESTART yet. so hit NO/Cancel
vi. Go to Control Panel and uninstall NVIDIA PhysX driver
Vii. Go back to My Computer C:\NVIDIA\(here you have two folders which are your chipset driver folder and your display driver folder.)
viii. Go to your display driver folder. Inside your display driver folder there is another folder, delete that.
ix. Empty Recycle bin
x. Download DriverSweeper:
http://downloads.guru3d.com/Guru3D--...er)_d1672.html and your new display driver
http://www.nvidia.com/Download/index.aspx?lang=en-us
4. . Restart your computer and boot to Safe Mode
5. Once in Safe Mode, open DriverSweeper and tick NVIDIA Display and click analyse/scan. Once finish scanning, Click Clean for several times. try to rescan it and clean it again.
6. Restart your computer. Once you get back to your desktop, install the new driver. And restart after driver finish installing.